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AMP

General Description

Name	Value
Level	S-1 / C-1
Discovered	1975 / A. hentzi & Aphonopelma sp.
Synonym
Molecular formula	C₁₀H₁₄N₅O₇P
CAS	61-19-8
SMILES	`OC1[C@@H](COP(O)(O)=O)O[C@@H](N2C=NC3=C2N=CN=C3N)C1O`
InChI	`InChI=1S/C10H14N5O7P/c11-8-5-9(13-2-12-8)15(3-14-5)10-7(17)6(16)4(22-10)1-21-23(18,19)20/h2-4,6-7,10,16-17H,1H2,(H2,11,12,13)(H2,18,19,20)/t4-,6+,7?,10-/m1/s1`

Precursor 1 [M+H]⁺	348.07036
Precursor 2
Precursor 3

HDX	6
Precursor HDX 1 [M(D₆)+D]⁺	355.11430
Precursor HDX 2
Precursor HDX 3

Rt	1.42 (broad)
Rt HDX

MS/MS fragments

m/z	Molecular formula	Annotation
348.07036	C₁₀H₁₅N₅O₇P	[M+H]⁺
136.06177	C₅H₆N₅	[adenine+H]⁺

Recorded MS/MS spectra

pdf	Precursor	Co-eluting	Spider	Source	Author
Data	348.07036		Adenosine-5’-monophosphate, disodium salt (CAS 4578-31-8)	Fluka	Y. M. Forster

References

Title	Reference	Spider	Name	Content	Link
Adenosine triphosphate in tarantula spider venoms and its synergistic effect with the venom toxin	T. K. Chan, C. R. Geren, D. E. Howell, G. V. Odell, Toxicon 1975, 13, 1, 61-66	A. hentzi & Aphonopelma sp.			Link
Biochemical analysis of tarantula venom (Eurypelma californicum)	A. Savel-Niemann, D. Roth, Naturwissenschaften 1989, 76, 5, 212-213	A. californicum			Link
Tarantula (Eurypelma californicum) venom, a multicomponent system	A. Savel-Niemann, Biol. Chem. 1989, 370, 1, 485-498	A. californicum			Link
ADP is a vasodilator component from Lasiodora sp. mygalomorph spider venom	C. C. Horta, B. A. Rezende, B. B. R. Oliveira-Mendes, A. O. Carmo, L. S. A. Capettini, J. F. Silva, M. T. Gomes, C. V. Chavez-Olortegui, C. E. S. Bravo, V. S. Lemos, E. Kalpothakis, Toxicon 2013, 72, 102-112	Lasiodora sp.			Link

Spider species

Spider species	Family	Discovered
Aphonopelma californicum	Theraphosidae	1989 / A. Savel-Niemann
Aphonopelma hentzi	Theraphosidae	1975 / T. K. Chan
Aphonopelma sp.	Theraphosidae	1975 / T. K. Chan
Lasiodora sp.	Theraphosidae	2013 / C. C. Horta

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