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ADP

General Description

Name	Value
Level	S-1 / C-2
Discovered	1975 / A. hentzi & Aphonopelma sp.
Synonym
Molecular formula	C₁₀H₁₅N₅O₁₀P₂
CAS	58-64-0
SMILES	`OC1[C@@H](COP(OP(O)(O)=O)(O)=O)O[C@@H](N2C=NC3=C2N=CN=C3N)C1O`
InChI	`InChI=1S/C10H15N5O10P2/c11-8-5-9(13-2-12-8)15(3-14-5)10-7(17)6(16)4(24-10)1-23-27(21,22)25-26(18,19)20/h2-4,6-7,10,16-17H,1H2,(H,21,22)(H2,11,12,13)(H2,18,19,20)/t4-,6+,7?,10-/m1/s1`

Precursor 1 [M+H]⁺	428.03669
Precursor 2
Precursor 3

HDX	7
Precursor HDX 1 [M(D₇)+D]⁺	436.08691
Precursor HDX 2
Precursor HDX 3

Rt
Rt HDX

MS/MS fragments

m/z	Molecular formula	Annotation
428.03724	C₁₀H₁₆N₅O₁₀P₂	[M+H]⁺
348.07091	C₁₀H₁₅N₅O₇P
136.06232	C₅H₆N₅	[adenine+H]⁺

Recorded MS/MS spectra

pdf	Precursor	Co-eluting	Spider	Source	Author

References

Title	Reference	Spider	Name	Content	Link
Adenosine triphosphate in tarantula spider venoms and its synergistic effect with the venom toxin	T. K. Chan, C. R. Geren, D. E. Howell, G. V. Odell, Toxicon 1975, 13, 1, 61-66	A. hentzi & Aphonopelma sp.	TLC		Link
Biochemical analysis of tarantula venom (Eurypelma californicum)	A. Savel-Niemann, D. Roth, Naturwissenschaften 1989, 76, 5, 212-213	A. californicum	HPLC		Link
Tarantula (Eurypelma californicum) venom, a multicomponent system	A. Savel-Niemann, Biol. Chem. 1989, 370, 1, 485-498	A. californicum	HPLC		Link
ADP is a vasodilator component from Lasiodora sp. mygalomorph spider venom	C. C. Horta, B. A. Rezende, B. B. R. Oliveira-Mendes, A. O. Carmo, L. S. A. Capettini, J. F. Silva, M. T. Gomes, C. V. Chavez-Olortegui, C. E. S. Bravo, V. S. Lemos, E. Kalpothakis, Toxicon 2013, 72, 102-112	Lasiodora sp.	isolation, ESI-MS/MS, NMR		Link

Spider species

Spider species	Family	Discovered
Aphonopelma californicum	Theraphosidae	1989 / A. Savel-Niemann
Aphonopelma hentzi	Theraphosidae	1975 / T. K. Chan
Aphonopelma sp.	Theraphosidae	1975 / T. K. Chan
Lasiodora sp.	Theraphosidae	2013 / C. C. Horta

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