PA4

General Description

NameValue
LevelS-1 / C-3
Discovered1980 / div.
SynonymPutrescine
Molecular formulaC₄H₁₂N₂
CAS110-60-1
SMILESNCCCCN
InChIInChI=1S/C4H12N2/c5-3-1-2-4-6/h1-6H2
Precursor 1 [M+H]⁺89.10732
Precursor 2 [M+2H]²⁺45.05730
Precursor 3
HDX4
Precursor HDX 1 [M(D₄)+D]⁺94.13871
Precursor HDX 2 [M(D₄)+2D]²⁺48.07613
Precursor HDX 3
Rt
Rt HDX

Calculated MS/MS fragments

#abctazytz
172.0807854.0702155.0542372.0813272.0807855.0542389.10732

Additional MS/MS fragments

m/zAnnotation

Recorded MS/MS spectra

pdfPrecursorCo-elutingSpiderSourceAuthor

References

TitleReferenceSpiderNameContentLink
Polyamines in some tarantula venomsS. G. Cabbiness, C. W. Gehrke, K. C. Kuo, T. K. Chan, J. E. Hall, S. A. Hudiburg, G. V. Odell, Toxicon 1980, 18, 681-683div.Link
Determination of biogenic amines in spider venom glands of nine typical Japanese species and chromatographic elution pattern analysis of venomous componentsK. Hagiwara, A. Tokita, A. Miwa, N. Kawai, Y. Murata, A. Uchida, T. Nakajima, Jpn. J. Sanit. Zool. 1991, 42, 2, 77-84div.HPLClink
Novel linear and branched polyamines in the extremely thermophilic eubacteria Thermoleophilum, Bacillus and HydrogenobacterK. Hamana, M. Niitsu, S. Matsuzaki, K. Samejima, Y. Igarashi, T. Kodama, Biochem. J. 1992, 284, 741-747HPLC, GCLink
The components of the venom of a spider Scodra griseipes. 1. Analysis of low molecular weight products using gas chromatography/ mass spectrometryC. Lange, C. Paris, M.-L. Celerier, Rapid Commun. Mass Spectrom. 1992, 6, 289-292S. calceatum griseipesGC-MSlink
Purification of toxic peptides and the amino acid sequence of CSTX-1 from the multicomponent venom of Cupiennius salei (Araneae: Ctenidae)L. Kuhn-Nentwig, J. Schaller, W. Nentwig, Toxicon 1994, 32, 3, 287-302C. saleiAmino acid analysislink
Polyamine analysis for chemotaxonomy of thermophilic eubacteria: Polyamine distribution profiles within the orders Aquificales, Thermotogales, Thermodesulfobacteriales, Thermales, Thermoanaerobacteriales, Clostridiales and BacillalesR. Hosoya, K. Hamana, M. Niitsu, T. Itho, J. Gen. Appl. Microbiol. 2004, 50, 271-287HPLC, GCLink
Venom composition and strategies in spiders: Is everything possible?L. Kuhn-Nentwig, R. Stöcklin, W. Nentwig, Adv. Insect Physiol. 2011, 40, 1-86.putrescineReviewLink

Spider species

Spider speciesFamilyDiscovered
Aphonopelma emilia*Theraphosidae1980 / S. G. Cabbiness
Aphonopelma hentziTheraphosidae1980 / S. G. Cabbiness
Aphonopelma sp.Theraphosidae1980 / S. G. Cabbiness
Argiope bruennichiAraneidae1991 / K. Hagiwara
Cupiennius saleiCtenidae1994 / L. Kuhn-Nentwig
Neoscona nauticaAraneidae1991 / K. Hagiwara
Nephila clavataAraneidae1991 / K. Hagiwara
Stromatopelma calceatum griseipesTheraphosidae1992 / C. Lange

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